Periodic Classification of Elements Assignment Solved
Ans. Dobereiner tried to arrange elements with similar properties into groups of 3 elements each. He called these as triads. He showed that when the 3 elements into a triad were arranged in the order of increasing atomic masses, the atomic mass of the middle element was roughly the average of the masses of the other two elements. e.g. Li Na K
Q2. What were the limitations of Dobereiner’s Law of triads?
Q3. State newland’s law of Octaves.
Q10. What is Modern periodic Law ?
Ans. The Properties of elements are a periodic function of their atomic number.
Q11. How were the drawbacks of Mendeleev's periodic table resolved in the modern periodic table?
Ans. As the modern periodic table was based on the atomic numbers so all the isotopes could be placed together in one slot. Secondly, the wrong order of atomic masses was also sorted as Cobalt's atomic number was lower than Nickel even though it had a higher atomic mass.
Q12. How are the position of elements related to their atomic number in the Modern periodic table?
Ans. The number of valence electrons present in an atom of an element is equivalent to the group number, while the total number of shells give the period number in which the element to present.
Q13. Explain the gradation in properties of elements in the modern periodic table.
Ans. a. Valency:
Ans. Dobereiner tried to arrange elements with similar properties into groups of 3 elements each. He called these as triads. He showed that when the 3 elements into a triad were arranged in the order of increasing atomic masses, the atomic mass of the middle element was roughly the average of the masses of the other two elements. e.g. Li Na K
atomic mass 6.9 23 39
39+6.9/2 = 45.9/2 = 22.9 = 23
Q2. What were the limitations of Dobereiner’s Law of triads?
Ans. Dobereiner could identify only 3 triads from the element known at that time. Hence, this system is not useful.
Q3. State newland’s law of Octaves.
Ans. Newland arranged the elements in the increasing order of the atomic masses and found that every eight element had properties similar to that of the first like the notes of music.
Q4. What were the limitations of newland’s Law of Octaves?
Ans. 1. It was only applicable only up to Calcium as after Calcium every eighth element did not posses , properties similar to that of first.
2. At a few places unlike elements were put together like cobalt and nickel along with F, Cl and Br.
Q5. Which 2 criteria did Mendeleev used to classify elements in his periodic table ?
Ans. Atomic mass and similarity in chemical property.
Q6. State Mendeleev’s periodic law.
Ans. Properties of elements are a periodic function of their atomic masses.
Q7. Why did Mendeleev leave gap in his periodic table?
Q7. Why did Mendeleev leave gap in his periodic table?
Ans. Mendeleev place elements with similar properties one below the other leaving gap for yet undiscovered elements.
Q8. Name the elements which have since been discovered that were left by Mendeleev in his Periodic Table?
Ans. Eka Boron – Scandium Eka Al - Gallium Eka Si - Germanium
Q9. What are the limitations of Mendeleev's periodic table?
Ans.
1. Position of Isotopes was not clear in his table.
1. Position of Isotopes was not clear in his table.
2. Wrong Order of atomic mass of certain elements – Elements with higher atomic mass were placed before elements having lower atomic mass. e.g. Cobalt was placed before nickel.
3. Position of hydrogen was not clear in his periodic table.
Q10. What is Modern periodic Law ?
Ans. The Properties of elements are a periodic function of their atomic number.
Q11. How were the drawbacks of Mendeleev's periodic table resolved in the modern periodic table?
Ans. As the modern periodic table was based on the atomic numbers so all the isotopes could be placed together in one slot. Secondly, the wrong order of atomic masses was also sorted as Cobalt's atomic number was lower than Nickel even though it had a higher atomic mass.
Q12. How are the position of elements related to their atomic number in the Modern periodic table?
Ans. The number of valence electrons present in an atom of an element is equivalent to the group number, while the total number of shells give the period number in which the element to present.
e.g 1. Atomic no. of Mg=12 ; Electronic configuration=2,8,2 therefore, Gp. no.=2 or IIA Period no.=3
e.g 2. Atomic no. of Cl=17; Electronic Configuration=2,8,7 therefore, Gp. no.=17th or VIIA
Q13. Explain the gradation in properties of elements in the modern periodic table.
Ans. a. Valency:
Valency of elements remain the same while going down a group
Moving across a period, the valency of elements increases from 1 to 4 and then decreases till 0.
b. Atomic size or radius:
It increases on going down a group
It decreases in Moving from left to right along a period.
c. Metallic and non-metallic properties: : Moving down a group of metals, metallic nature increases due to increasing size. However, in a group of non-metals the non-metallic character decreases on going down
Going across a period, the metallic character decreases while Non-metallic character increases
Q14. Give examples of somea. Metalloids – Boron , Silicon , Germanium
b. Alkali metals – Sodium , lithium , Potassium
c. Halogens – Fluorine , Chlorine , Bromine
d. Alkaline Earth metals – Magnesium , Calcium
e. Nobel gases or Inert elements – Helium , Neon , Krypton
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