An
organic acid ‘X’ is a liquid which often freezes during winter time in cold
countries, has the molecular formula, C2H4O2. On warming it with ethanol in the presence of a few
drops of concentrated sulphuric acid,
a compound ‘Y’ with a sweet smell is formed
(i) Identify ‘X’ and ‘Y’. (ii)
Write a chemical equation for the reaction involved.
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(i) The organic acid X is
ethanoic acid (CH3COOH) and The compound Y is ethyl Ethanoate
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CH3 – COOH + CH3
– CH2OH ----------> (CH3
– C – O – CH2 – CH3 )
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II
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O
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Write
name of the following –
i. Alkaline earth metal belonging to the third period
ii. The alkali metal atom having largest atomic radius
iii. The halogen atom belonging to fourth period
iv. The element having lowest ionization energy
v. The element having second lowest electronegativity
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i. Magnesium
ii. Francium
iii.
Bromine
iv.
Cesium
375.6 kJ per mole
v. Francium 380 kJ per mole
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Organic compound 'x' of molecular formula C2H4O2
gives brisk effervescence with sodium bi carbonate . give name and
molecular formula of x with balanced equation
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The compound X is ethanoic
acid, commonly known as acetic acid. On reaction with sodium bicarbonate, it
forms sodium acetate, water and carbon dioxide gas. Thus the brisk
effervescence observed is due to carbon dioxide gas. Its molecular formula is
C2H4O2 .
Following is the chemical
equation for the reaction
CH3COOH + NaHCO3 →
CH3COONa + H2O + CO2
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What is Saponification Reaction?
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Esters react in the presence
of an acid or a base to give back alcohol and carboxylic acid. This
reaction is used in the manufacture of soaps and is known as saponification.
Soap, is nothing but the sodium salt of the carboxylate.
CH3COOC2H5 ---(NaOH)--> CH3COOH +
C2H5OH
Ester (ethyl ethanoate) --Base (sodium
hydroxide)--> Carboxylic Acid (ethanoic acid) + Alcohol
(ethanol)
CH3COOH + NaOH -----> CH3COONa
+ H2O
Carboxylic Acid (Ethanoic Acid) + Base (Sodium Hydroxide)
-----> Soap (Sodium Ethanoate / acetate) + Water
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Soaps
are not considered as effective cleansing agent. Why?
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Soaps are not considered as
effective cleansing agent because it is glyceride salt of soft metal like
sodium which works in neutral and alkaline medium but in acidic medium get
neutralized to form scum or ppt.
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How
does melting and boiling points of hydrocarbon change with the increase in molecular
mass ?
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With increase in molar mass,
the melting point and boiling points of hydrocarbons increases generally.
It is because, with increase
in molar mass, the molecule becomes larger and so the van der waal's forces
and other binding forces between those molecules become stronger, which holds
the particles very firmly together in solid or liquid phase and so it
requires more energy to break these bonds and thus the melting and boiling
points of the hydrocarbons increases.
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Write
down the relevant chemical equation involved in decolourisation.
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Ethene is an unsaturated
compound.it has one double bond.When Bromine water(brown in colour) is added
to ethene it reacts with ethene to form a new compound 1,2 dibromoethane
which is colourless. The colour of bromine water is gone now. Generally
bromine water is decolourise by all the compounds that contain double or
triple bond. Ethane is a saturated compound with no multiple bond hence does
not decolourise Br water
CH2 = CH2 + Br2 ----------> Br-CH2
- CH2- Br
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A
compound X has molecular formula C3H4 one mole of X reacts with 2 moles of
hydrogen to yield a compound Y deduce the structure of X and Y.
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The molecular formula
suggests that the molecule is an alkyne, as the general formula for alkyne is
CnH2n-2. So, X is propyne. Addition of two moles of
hydrogen will form the corresponding alkane, propane (C3H6).
So, X is propyne and Y is propane.
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HC º C - CH3 + 2 H2
--------------> CH3 - C H2- CH3
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What is
dehydration reaction? Give one example.
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The removal of water molecule
from a compound is known as dehydration. Example: Dehydration of alcohols
gives alkenes.
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R-CH2-CHOH-R ------------->
R-CH=CH-R + H2O
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What is
hydrolysis?
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Hydrolysis means addition of
water to a molecule resulting in breaking of bonds that are present in the
molecule.
In scientific language;-
Hydrolysis
is a type of decomposition
reaction where one reactant is water.
The general formula of a hydrolysis reaction
is:
AB + H2O → AH + BOH
Organic hydrolysis reactions involve the
reaction of water and a ester.
This reaction follows the general formula:
RCO-OR' + H20 → RCO-OH + R'-OH
Dissolving a salt of a weak
acid or base in water is an example of a hydrolysis reaction.
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Why doesn’t
soap form micelles in ethanol as they form in water?
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A molecule of soap is made up
of two parts- a hydrophilic polar end and a hydrophobic hydrocarbon
part.In a soap solution, the hydrocarbon portion of several soap molecules
huddle together whereas the polar ends project outward into the polar
solvent, water. These spherical clusters of hundreds of molecules are called
micelle.
In organic solvent like
ethanol, soap is completely soluble, hence no micelle formation
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Three
elements X,Y and Z belong to 17TH group but to 2nd 3th and 4th period
respectively. Number of valance electrons in X is 7Find the number of valance
electrons in X and Z.
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Since X, Y and Z all three
belong to same group that is 17th therefore they all have
same number of valence electrons which is equal to 7. Having different period will
not affect on the number of valence electrons provided the group number
remain same.
The X, Y and Z are Fluorine, chlorine and bromine belonging to 2nd,
3rd and 4th period respectively.
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What is
the use of oxyacetylene flame?
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The oxyacetylene flame is a
gas torch that burns a mixture of acetylene and oxygen to produce a
high-temperature flame (3,000°C or 5,400°F) that can be used for
welding, cutting steel, and other metal working.
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What is
observed on adding 5% solution of alkaline potassium permanganate solution
drop by drop to some warm ethanol taken in testube.
Write
the name of the compound formed during chemical reaction.
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When a 5% solution of
alkaline potassium permanganate solution is added drop by drop to some warm ethanol taken in a test
tube, magenta colour of alkaline potassium
permanganate disappears and ethanol has been changed to carboxylic acid
. The reaction is as follows.
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CH3 - CH2OH --------------- > CH3COOH
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How
would you distinguish experimentally between an alcohol and a carboxylic acid
on the basis of a chemical property?
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To distinguish experimentally
between an alcohol and a carboxylic acid on the basis of a chemical property,
we take these samples in two separate test tubes. Add sodium hydrogen
carbonate in both the test tubes. The test tube, from which the effectiveness
evolves, contain carboxylic acid. The effervescence is due to the evolution
of carbon dioxide gas. However, from test
tube containing alcohol there is to effervescence, because no carbon dioxide gas is produced there.
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Why are
vegetable oils healthy as compared to vegetable ghee ? how are vegetable oils
converted into vegetable ghee name the process.
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The fatty acid with a single
double bond is called mono unsaturated fatty acid (e.g. oleic acid), and if
it has multiple double bonds, it’s polyunsaturated (e.g. linoleic acid). By
virtue of their tightly packed structure, the saturated fatty acids increase
the levels of bad cholesterol (LDL) and clog the arteries. On the other hand,
the unsaturated fatty acids increase
the levels of good cholesterol (HDL) by taking the LDL to the liver to be
broken down and removed from the body.
Vegetable oil can be converted
into ghee by the process of hydrogenation.
The
process of conversion of oil into ghee is known hydrogenation. This process
is called so because hydrogen is added and it takes place at 4500c
and with nickel or palladium as a catalyst.
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CH2=CH2 +H2 ----Ni---------> CH3-CH3
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When
acetic acid reacts with X, a salt is formed which on reaction with soda lime
gives a gas Y. Identify X and Y
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CH3COOH + NaHCO3
--------------> CH3COONa + H2O +CO2
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CH3COONa
+NaOH ---------- -> CH4 + Na 2 CO3
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“Alkenes
form a homologous series" Explain.
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Homologous series is a group
or family of compounds that have the same general formula but vary by a single
parameter.
Alkenes have general formula, CnH2n and the
varying parameter is the length of carbon chain. C2H4,
C3H6, C4H8 are members with
different number of carbon atoms.
For more Guess paper visit
CBSE SUMMATIVE ASSESSMENT-II SAMPLE PAPER 2014 Class Xth [Links]
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CBSE SUMMATIVE ASSESSMENT-II SAMPLE PAPER 2014 Class IXth [Links]
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Q 1. Justify the nature of physical and chemical properties of the compound of homologous series -2
CBSE 2013-14
A Homologous Series is a group of organic chemical compounds, usually listed in order of increasing size, that have a similar structure (and hence also similar properties) and whose structures differ only by the number of CH2 units in the main carbon chain.
1. Chemical Properties
Organic compounds that are part of the same homologous series generally have similar chemical properties as each other, due to the presence of the same functional group in the molecules of all compounds in the series.
2. Physical Properties
The physical property of any particular member of a homologous series depends on its size, or its position within the homologous series. The physical properties, such as solubility, melting point, boiling point, specific gravity etc. show a gradual change with the increase in their relative molecular masses.
Q 2. Apart from organic being where else we find carbon? Mention the form in which it is available there and also its percentage
Apart from organic being we find carbon in the earth’s crust about 0.02% in the form of minerals like carbonates, hydrogen carbonates, coal and petroleum CBSE 2013-14
Q3. How are carboxylic acids from mineral acid on the basis of ionization point of view?
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